Synthesis, Characterization, and Crystal Structure Determination of Iron(III) Hetero-ligand Complex Containing Chloride, Dimethyl sulfoxide, pyridine-2, 6-dicarboxylate and Water, [Fe(Pydc)(DMSO)(H2O)Cl]
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Abstract:
A new metal-organic compound, [Fe(Pydc)(DMSO)(H2O)Cl], (where Pydc is pyridine-2, 6-dicarboxylate and DMSO is dimethyl sulfoxide), has been synthesized and characterized by singlecrystal X-ray diffraction, TGA/DTA, IR and Raman spectroscopy. Green-yellow crystals,crystallized in the monoclinic system, space group P21/n, a = 7.2461(4) Å, b = 10.3018(4) Å, c =17.7667(10) Å, α = 90°, β = 90.014°(5), 1329.54(12) Å3, Z = 4 and R = 0.0317. In the molecule ofthe crystallized compound Fe ion is sixfold coordinated with distorted octahedral geometry andthe structure is stabilized by O-H…O hydrogen bonds.
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Journal title
volume 4 issue 3
pages 45- 51
publication date 2007-11-01
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